[3.14] gh-142965: Fix Concatenate documentation to reflect valid use cases (GH-143316) (#148899)

The documentation previously stated that Concatenate is only valid
when used as the first argument to Callable, but according to PEP 612,
it can also be used when instantiating user-defined generic classes
with ParamSpec parameters.
(cherry picked from commit 75ff1af)

Co-authored-by: John Seong <39040639+sandole@users.noreply.github.com>

Author: miss-islington

Doc/library/typing.rst

@@ -1174,7 +1174,8 @@ These can be used as types in annotations. They all support subscription using
    or transforms parameters of another
    callable.  Usage is in the form
    ``Concatenate[Arg1Type, Arg2Type, ..., ParamSpecVariable]``. ``Concatenate``
-   is currently only valid when used as the first argument to a :ref:`Callable <annotating-callables>`.
+   is valid when used in :ref:`Callable <annotating-callables>` type hints
+   and when instantiating user-defined generic classes with :class:`ParamSpec` parameters.
    The last parameter to ``Concatenate`` must be a :class:`ParamSpec` or
    ellipsis (``...``).